Colored photosensistive resin composition, coating film of colored photosensitive resin composition, photosensitive resin transfer material, method of foaming photosensitive resin layer, color filter, method for producing color filter, and liquid crystal display device

ABSTRACT

A colored photosensitive resin composition comprising (1) an alkali-soluble binder, (2) a monomer or an oligomer, (3) a photopolymerizaton initiator or a photopolymerization initiator system, and (4) a coloring agent, wherein the coloring agent is a specific pigment in a specific quantity. Also provided is a color filter obtained by using the colored photosensitive resin compositions for formation of the respective photosensitive resin layers of R, G and B.

CROSS-REFERENCE TO RELATED APPLICATION

This application claims priority under 35 USC 119 from Japanese patentApplication Nos. 2004-181587 and 2005-060629, the disclosures of whichare incorporated by reference herein.

BACKGROUND OF THE INVENTION

1. Filed of the Invention

The present invention relates to a color filter which is suitably usedalso in a large-screen liquid crystal display device such as a notebookcomputer and a television monitor, to a method for producing the colorfilter, to a photosensitive resin transfer material which is used in thecolor filter and in the method for producing the color filter, to amethod of forming a photosensitive resin layer using the photosensitiveresin transfer material, to a colored photosensitive resin compositionused in the color filter and in the method for producing the colorfilter and the photosensitive resin transfer material, to a coating filmof the colored photosensitive resin composition, and to a liquid displaydevice using the color filter.

2. Description of the Related Art

A color filter is an essential constitutional member in a liquid crystaldisplay (hereinafter, also referred to as “liquid crystal displaydevice”). This liquid crystal display is very compact, and equivalent toor superior over a CRT display also in performance, and a CRT display isincreasingly replaced by a liquid crystal display.

In formation of a color image on a liquid crystal display, light whichhas passed through a color filter is, as it is, colored into a color ofeach pixel constituting the color filter, and lights of those colors arecombined to form a color image. Currently, a color image is formed ofpixels of three colors of RGB.

In recent years, technical development of a liquid crystal display witha larger area and higher-definition has progressed, and its utility hasbeen extended to a notebook computer display, a desktop personalcomputer monitor, and a television monitor. Under such circumstances,higher color purity is required also in a color filter used in a liquidcrystal display.

However, in conventional large screen color filters (such as colorfilters disclosed in Japanese Patent Application Laid-Open (JP-A) No.2004-126549), sufficient color purity has not been obtained, and therehave been needs for further improvement.

SUMMARY OF THE INVENTION

The present invention provides a color filter with superior chromaticitywhich can realize a high color purity even when used in a large screenliquid crystal display device such as a notebook computer display and atelevision monitor. The invention also provides a method for producingthe color filter. The invention further provides a photosensitive resintransfer material which is suitably used in the color filter and in themethod for producing the color filter, and a method of forming aphotosensitive resin layer using the photosensitive resin transfermaterial. The invention further provides a colored photosensitive resincomposition which is suitably used in the color filter, in the methodfor producing the color filter, and in the photosensitive resin transfermaterial. The invention still further provides a coating film of thecolored photosensitive resin composition, and a liquid crystal displaydevice using the color filter.

A first aspect of the invention is to provide a colored photosensitiveresin composition comprising an alkali-soluble binder, a monomer or anoligomer, a photopolymerization initiator or a photopolymerizationinitiator system, and a coloring agent. The coloring agent comprises apigment C.I.P.R.254 and a pigment C.I.P.R.177. The content of thepigment C.I.P.R.254 is 0.80 to 0.96 g/m² in a dried film with a filmthickness of 1 to 3 μm obtained by coating and drying the coloredphotosensitive resin composition. The content of the pigment C.I.P.R.177is 0.20 to 0.24 g/m² in the dried film.

A second aspect of the invention is to provide a colored photosensitiveresin composition comprising an alkali soluble binder, a monomer or anoligomer, a photopolymerization initiator or a photopolymerizationinitiator system, and a coloring agent. The coloring agent comprises apigment C.I.P.G.36 and a pigment C.I.P.Y.150. The content of the pigmentC.I.P.G. 36 is 0.90 to 1.34 g/m² in a dried film with a film thicknessof 1 to 3 μm obtained by coating and drying the colored photosensitiveresin composition. The content of the pigment C.I.P.Y.150 is 0.38 to0.58 g/m² in the dried film.

A third aspect of the invention is to provide a colored photosensitiveresin composition comprising an alkali-soluble binder, a monomer or anoligomer, a photopolymerization initiator or a photopolymerizationinitiator system, and a coloring agent. The coloring agent comprises apigment C.I.P.B.15:6 and a pigment C.I.P.V.23. The content of thepigment C.I.P.B.15:6 is 0.59 to 0.67 g/m² in a dried film with a filmthickness of 1 to 3 μm obtained by coating and drying the coloredphotosensitive resin composition, and the content of the pigmentC.I.P.V.23 is 0.065 to 0.075 g/m² in the dried film.

The above colored photosensitive resin compositions each may contain asurfactant.

The above colored photosensitive resin composition each may furthercomprise at least two types of photopolymerization initiators as thephotopolymerization initiator or as the photopolymerization initiatorsystem.

A fourth aspect of the invention is to provide a photosensitive resintransfer material comprising a photosensitive resin layer formed on atemporary support by using any of the above colored photosensitive resincompositions.

A fifth aspect of the invention is to provide a coating film. Thecoating film comprises a colored photosensitive resin compositioncomprising an alkali-soluble binder, a monomer or an oligomer, aphotopolymerization initiator or a photopolymerization initiator system,and a coloring agent. The coloring agent comprises a pigment C.I.P.R.254and a pigment C.I.P.R.177. The content of the pigment C.I.P.R.254 in thecoating film is 0.80 to 0.96 g/m². The content of the pigmentC.I.P.R.177 in the coating film is 0.20 to 0.24 g/m².

A sixth aspect of the invention is to provide a coating film. Thecoating film comprises a colored photosensitive resin compositioncomprising an alkali soluble binder, a monomer or an oligomer, aphotopolymerization initiator or a photopolymerization initiator system,and a coloring agent. The coloring agent comprises a pigment C.I.P.G.36and a pigment C.I.P.Y150. The content of the pigment C.I.P.G. 36 in thecoating film is 0.90 to 1.34 g/m². The content of the pigment C.I.P.Y150in the coating film is 0.38 to 0.58 g/m².

A seventh aspect of the invention is to provide a coating film. Thecoating film comprises a colored photosensitive resin compositioncomprising an alkali-soluble binder, a monomer or an oligomer, aphotopolymerization initiator or a photopolymerization initiator system,and a coloring agent. The coloring agent comprises a pigmentC.I.P.B.15:6 and a pigment C.I.P.V.23. The content of the pigmentC.I.P.B.15:6 in the coating film is 0.59 to 0.67 g/m², and the contentof the pigment C.I.P.V.23 in the coating film is 0.065 to 0.075 g/m².

The above coating films each may further comprise at least two types ofphotopolymerization initiators as the photopolymerization initiator oras the photopolymerization initiator system.

The above coating films each may be formed by: coating the coloredphotosensitive resin composition by using a slit nozzle, and drying thecolored photosensitive resin composition.

An eighth aspect of the invention is to provide a color filter. Thecolor filter comprises a red (R) photosensitive resin layer, a green (G)photosensitive resin layer, and a blue (B) photosensitive resin layer.The red (R) photosensitive resin layer may comprise the coloredphotosensitive resin composition of the first aspect. The green (G)photosensitive resin layer may comprise the colored photosensitive resincomposition of the second aspect. The blue (B) photosensitive resinlayer may comprise the colored photosensitive resin composition of thethird aspect.

A ninth aspect of the invention is to provide a color filter. The colorfilter comprises a red (R) photosensitive resin layer, a green (G)photosensitive resin layer, and a blue (B) photosensitive resin layer.The red (R) photosensitive resin layer may comprise the coating film ofthe fifth aspect. The green (G) photosensitive resin layer may comprisethe coating film of the sixth aspect. The blue (B) photosensitive resinlayer may comprise the coating film of the seventh aspect.

A tenth aspect of the invention is to provide a method of forming aphotosensitive resin layer, the method comprising adhering thephotosensitive resin transfer material of the fourth aspect to asubstrate by a laminator.

An eleventh aspect of the invention is to provide a method for producinga color filter. The method comprises forming a photosensitive resinlayer, exposing the photosensitive resin layer, developing thephotosensitive resin layer, and baking the photosensitive resin layer.The photosensitive resin layer may comprise any of the above coloredphotosensitive resin compositions or any of the above coating films, orthe photosensitive resin layer may be formed by the method of the tenthaspect. The invention also provides a color filter produced by themethod.

A twelfth aspect of the invention is to provide a liquid crystal displaydevice using the above color filter.

DETAILED DESCRIPTION OF THE INVENTION

First, a colored photosensitive resin composition of the presentinvention will be explained. Thereafter, a coating film of the coloredphotosensitive resin composition, a photosensitive resin transfermaterial, a color filter, production methods thereof, and a liquidcrystal display device of the invention will be described sequentially.

<Colored Photosensitive Resin Composition>

The colored photosensitive resin composition of the invention is acolored photosensitive composition comprising at least (1) analkali-soluble binder (2) a monomer or a oligomer, (3) aphotopolymerization initiator or a photopolymerization initiator system,and (4) a coloring agent, wherein a specified pigment is used as thecoloring agent at a specific content. In the specification, sometimes,the content of the pigment in the colored photosensitive composition isexpressed in terms of the quantity in a dry film having a thickness of 1to 3 μm. Such an expression is intended to mean that there exists a dryfilm thickness within the range of 1 to 3 μm at which the quantity ofthe pigment is within the specified range. Accordingly, the quantity ofthe pigment may not be always within the specified range throughout theentire dry film thickness range of 1 to 3 μm.

First, essential components (1) to (4) will be explained.

(1) Alkali-Soluble Binder

The alkali-soluble binder (hereinafter, simply referred to as “binder”in some cases) used in the invention is preferably a polymer having apolar group such as a carboxylic acid group or a carboxylate group on aside chain thereof. Examples thereof include a metahcrylic acidcopolymer, an acrylic acid copolymer, an itaconic acid copolymer, acrotonic acid copolymer, a maleic acid copolymer, and apartially-esterified maleic acid copolymer. Such copolymers aredisclosed, for example, in JP-A No. 59-44615, Japanese PatentPublication (JP-B) No. 54-34327, JP-B No. 58-12577, JP-B No. 54-25957,JP-A No. 59-53836 and JP-A No. 59-71048, the disclosures of which areincorporated herein by reference. Examples of the alkali-soluble binderfurther include a cellulose derivative having a carboxylic acid group ona side chain thereof and a polymer obtained by adding a cyclic acidanhydride to a polymer having a hydroxyl group. Particularly preferableexamples include a copolymer of benzyl (meth)acryalte and (meth)acrylicacid, and a multi-component copolymer of benzyl (meth)acrylate,(meth)acrylic acid and other monomers, such as the copolymers describedin U.S. Pat. No. 4,139,391, the disclosure of which is incorporatedherein by reference. These binder polymers having polar groups each maybe used alone or may be contained in a composition which also contains ausual film-forming polymer. The proportion of the colored photosensitiveresin composition to the total solid content is generally 20 to 50% bymass, preferably 25 to 45% by mass.

(2) Monomer or Oligomer

The monomer or oligomer used in the invention is preferably a monomer oroligomer which has two or more ethylenic unsaturated double bonds andwhich is addition-polymerized by irradiation with light. The monomer oroligomer may be a compound having at least one addition-polymerizableethylenic unsaturated group therein and having a boiling point of 100°C. or higher at a normal pressure. Examples thereof include: amonofunctional acrylate and a monofunctional methacryalte such aspolyethylene glycol mono(meth)acrylate, polypropylene glycolmono(meth)acryalte and phenoxyethyl (meth)acrylate; polyethylene glycoldi(meth)acryalte, polypropylene glycol di(meth)acrylate,trimethylolethane triacrylate, trimethylolpropane tri(meth)acrylate,trimethylolpropane diacrylate, neopentyl glycol di(meth)acrylate,pentaerythritol tetra(meth)acryalte, pentaerythritol tri(meth)acrylate,dipentaerythritol hexa(meth)acryalte, dipentaerythritolpenta(meth)acrylate, hexanediol di(meth)acrylate, trimethylolpropanetri(acryloyloxypropyl)ether, tri(acryloyloxyethyl)isocyanurate,tri(acryloyloxyethyl)cyanurate, glycerin tri(meth)acrylate; apolyfunctional acrylate or polyfunctional methacrylate which may beobtained by adding ethylene oxide or propylene oxide to a polyfunctionalalcohol such as polymethylolpropane or glycerin and converting theadduct into a (meth)acrylate.

Examples of the monomer and oligomer further include an urethaneacrylate such as urethane acrylates described in JP-B No. 48-41708, JP-BNo. 50-6034 and JP-A No. 51-37193 (the disclosures of which areincorporated herein by reference), and a polyester acrylate such aspolyester acrylates described in JP-A 48-64183, JP-B 49-43191, and JP-B52-30490 (the disclosures of which are incorporated herein byreference); a polyfunctional acrylate or polyfunctional methacrylatesuch as an epoxy acrylate which is a product of reaction of an epoxyresin and (meth)acrylic acid.

Among them, trimethylolpropane tri(meth)acrylate, pentaerythritoltetra(meth)acrylate, dipentaerythritol hexa(meth)acrylate, anddipentaerythritol penta(meth)acrylate are preferable.

Additionally, “polymerizable compound B” described in JP-A No. 11-133600(the disclosure of which is incorporated herein by reference) is alsopreferable.

These monomers and oligomers each may be used alone. Alternatively, amixture of two or more selected from these monomers and oligomers may beused. The proportion of the colored photosensitive resin composition tothe total solid content is generally 5 to 50% by mass, preferably 10 to40% by mass.

(3) Photopolymerization Initiator or Photopolymerization InitiatorSystem

Examples of a photopolymerization initiator or a photopolymerizationinitiator system in the invention include a vicinal polyketaldonylcompound such as vicinal polyketaldonyl compounds disclosed in U.S. Pat.No. 2,367,660 (the disclosure of which is incorporated herein byreference), an acyloin ether compound such as acyloin ether compoundsdescribed in U.S. Pat. No. 2,448,828 (the disclosure of which isincorporated herein by reference), an aromatic acyloin compoundsubstituted by an α-hydrocarbon such as described in U.S. Pat. No.2,722,512 (the disclosure of which is incorporated herein by reference),a polynuclear quinine compound such as described in U.S. Pat. No.3,046,127 and U.S. Pat. No. 2,951,758 (the disclosures of which areincorporated herein by reference), a combination of triarylimidazoledimer and p-ketone such as described in U.S. Pat. No. 3,549,367 (thedisclosure of which is incorporated herein by reference), abenzothiazole compound and a trihalomethyl-s-triazine compound such asdescribed in JP-B No. 51-48516 (the disclosure of which is incorporatedherein by reference), a trihalomethyl-triazine compound such asdescribed in U.S. Pat. No. 4,239,850 (the disclosure of which isincorporated herein by reference), and a trihalomethyloxadiazolecompound such as described in U.S. Pat. No. 4,212,976 (the disclosure ofwhich is incorporated herein by reference). In particular,trihalomethyl-s-triazine, trihalomethyloxadiazole and triarylimidazoledimer are preferable.

Additionally, “polymerization initiator C” described in JP-A No.11-133600 (the disclosure of which is incorporated herein by reference)is also preferable.

These photopolymerization initiators and photopolymerization initiatorsystem each may be used alone. Alternatively, a mixture of two or moreselected from these photopolymerizable initiators andphotopolymerization initiator systems may be used. It is preferable touse two or more selected from photopolymerizable initiators andphotopolymerization initiator systems. When two or more selected fromphotopolymerizable initiators and photopolymerization initiator systemsare used, the display property, particularly evenness of display, can beimproved.

The proportion of the photopolymerization initiator andphotopolymerization initiator system to the total solid content of thecolored photosensitive resin composition is generally 0.5 to 20% bymass, preferably 1 to 15% by mass.

(4) Coloring Agent

In the invention, (i) the red (R)-colored photosensitive resincomposition comprises C.I.Pigment red (C.I.P.R.) 254 and C.I.Pigment red(C.I.P.R)177 as the coloring agents; (ii) the green (G)-coloredphotosensitive resin composition comprises C.I.Pigment green (C.I.P.G)36 and C.I.Pigment yellow (C.I.P.Y)150 as the coloring agents; and (iii)the blue (B)-colored photosensitive resin composition comprisesC.I.Pigment blue (C.I.P.B)15:6 and C,I,Pitment violet (C.I.P.V.)23 asthe coloring agents.

When a dry film of the (i) red-colored photosensitive resin compositionwith a thickness of 1 to 3 μm is formed, the content of C.I.P.R.254 inthe dry film is 0.80 to 0.96 g/m², preferably 0.82 to 0.94 g/m², morepreferably 0.84 to 0.92 g/m².

When a dry film of the (i) red-colored photosensitive resin compositionwith a thickness of 1 to 3 μm is formed, the content of C.I.P.R. 177 inthe dry film is 0.20 to 0.24 g/m², preferably 0.21 to 0.23 g/m², morepreferably 0.215 to 0.225 g/m².

When a dry film of the (ii) green-colored photosensitive resincomposition with a thickness of 1 to 3 μm is formed, the content ofC.I.P.G36 in the dry film is 0.90 to 1.34 g/m², preferably 0.95 to 1.29g/m², more preferably 1.01 to 1.23 g/m².

When a dry film of the (ii) green-colored photosensitive resincomposition with a thickness of 1 to 3 μm is formed, the content ofC.I.P.Y150 in the dry film is 0.38 to 0.58 g/m², preferably 0.40 to 0.56g/m², more preferably 0.43 to 0.53 g/m².

When a dry film of the (iii) blue-colored photosensitive resincomposition with a thickness of 1 to 3 μm is formed, the content ofC.I.P.B.15:6 in the dry film is 0.59 to 0.67 g/m², preferably 0.60 to0.66 g/m², more preferably 0.61 to 0.65 g/m².

When a dry film of the (iii) blue-colored photosensitive resincomposition with a thickness of 1 to 3 μm is formed, the content ofC.I.P.V.23 in the dry film is 0.065 to 0.075 g/m², preferably 0.066 to0.074 g/m², more preferably 0.067 to 0.073 g/m².

These pigments are each preferably used preferably in the form of adispersion liquid. This dispersion liquid can be prepared by: adding acomposition obtained by mixing the pigment and a pigment dispersant toan organic solvent (or a vehicle) described later, and dispersing thecomposition in the organic solvent (or the vehicle). The vehicle refersto the medium dispersing the pigment when a paint is in the liquidstate, and includes a liquid component (binder) which binds to thepigment to solidify the coating film, and a component (organic solvent)which dissolves and dilutes the binder. The dispersing machine used fordispersing the pigment is not particularly limited, and examples thereofinclude known dispersing machines such as a kneader, a roll mill, anattritor, a supermill, a dissolver, a homomixer and a sand mill.

The coloring agent (pigment) used in the invention has a particlediameter of preferably 0.1 μm or smaller, more preferably 0.08 μm orsmaller.

(Other Additives)

-Solvent-

The colored photosensitive resin composition of the invention maycomprise an organic solvent, in addition to the aforementionedcomponents. Examples of the organic solvent include methyl ethyl ketone,propylene glycol monomethyl ether, propylene glycol monomethyl etheracetate, cyclohexanone, cyclohexanol, methyl isobutyl ketone, ethyllactate, methyl lactate, and caprolactam.

-Surfactant-

In conventional color filters, there was a problem that the color ofeach pixel is deep in order to realize a high color purity, wherebyunevenness of the film thickness of pixels is directly recognized ascolor unevenness. For this reason, suppression of the film thicknessvariation upon formation (coating) of a photosensitive resin layer hasbeen desired which directly influences the film thickness of pixels.

In the color filter of the invention or the photosensitive resintransfer material of the invention, the colored photosensitive resincomposition preferably comprises a suitable surfactant in order toachieve a uniform film thickness and in order to prevent the coatingunevenness (color unevenness caused by variation in the film thickness)effectively.

Preferable examples of the surfactant include surfactants disclosed inJP-A No. 2003-337424 and JP-A No. 11-133600, the disclosures of whichare incorporated herein by reference.

-Thermal Polymerization Inhibitor-

In a preferable embodiment, the colored photosensitive resin compositionof the invention includes a thermal polymerization inhibitor. Examplesof the thermal polymerization inhibitor include hydroquinone,hydroquinone monomethyl ether, p-methoxyphenol, di-t-butyl-p-cresol,pyrogallol, t-butylcatechol, benzoquinone,4,4′-thiobis(3-methyl-6-t-butylphenol),2,2′-methylenebis(4-methyl-6-t-butylphenol), 2-mercaptobenzimidazole,and phenothiazine.

-Dye and Pigment to be used Supplementarily-

If necessary, in addition to the aforementioned coloring agent(pigment), the colored photosensitive resin composition of the inventionmay further include a known coloring agent (a dye or a pigment) as longas the effect of the invention is not deteriorated. When the knowncoloring agent is a pigment, the pigment is preferably dispersed in thecolored photosensitive resin composition uniformly; therefore, theparticle diameter of such a pigment is preferably 0.1 μm or smaller,more preferably 0.08 μm or smaller.

Examples of the known dye and pigment include the colorants disclosed inparagraphs [0038] to [0040] of JP-A No. 2005-17716 (the disclosure ofwhich is incorporated herein by reference), in paragraphs [0068] to[0072] of JP-A No. 2005-361447 (the disclosure of which is incorporatedherein by reference), and in paragraphs [0080] to [0088] of JP-A No.2005-17521 (the disclosure of which is incorporated herein byreference).

-Ultraviolet-Ray Absorber-

If necessary, the colored photosensitive resin composition of theinvention may include an ultraviolet-ray absorber. Examples of theultraviolet-ray absorber include compounds disclosed in JP-A No. 5-72724(the disclosure of which is incorporated herein by reference), asalicylate-based ultraviolet-ray absorber, a benzophenone-basedultraviolet-ray absorber, a benzotriazole-based ultraviolet-rayabsorber, a cyanoacrylate-based ultraviolet-ray absorber, anickel-chelate-based ultraviolet-ray absorber, and ahindered-amine-based ultraviolet-ray absorber.

Specific examples thereof include phenyl salicylate, 4-t-butylphenylsalicylate, 2,4-di-t-butyl phenyl-3′,5′-di-t-4′-hydroxybenzoate,4-t-butyl phenylsalicylate, 2,4-dihydroxybenzophenone,2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-n-octoxybenzophenone,2-(2′-hydroxy-5′-methylphenyl)benzotriazole,2-(2′-hydroxy-3′-t-butyl-5′-methylphenyl)-5-chlorobenzotriazole,ethyl-2-cyano-3,3-diphenyl acrylate, 2,2′-hydroxy-4-methoxybenzophenone,nickel dibutyl dithiocarbamate,bis(2,2,6,6-tetramethyl-4-pyridine)-sebacate, 4-t-butylphenylsalicylate, phenyl salicylate,4-hydroxy-2,2,6,6-tetramethylpiperidine condensate, succinicacid-bis(2,2,6,6-tetramethyl-4-piperidenyl)-ester,2-[2-hydroxy-3,5-bis(α, α-dimethylbenzyl)phenyl]-2H-benzotriazole, and7-{[4-chloro-6-(diethylamino)-5-triazine-2-yl]amino }-3-phenylcoumarin.

In addition to the aforementioned additives, the colored photosensitiveresin composition of the invention may further include an “adhesionauxiliary” described in JP-A No. 11-133600 (the disclosure of which isincorporated herein by reference) and other additives.

<Coating Film of Colored Photosensitive Resin Composition>

The coating film of the invention made of a colored photosensitive resincomposition is a coating film of a colored photosensitive resincomposition comprising at least (1) an alkali-soluble binder, (2) amonomer or an oligomer, (3) a photopolymerization initiator or aphotopolymerization initiator system, and (4) a coloring agent, whereina specific pigment in a specific amount is used as the coloring agent.

The essential components (1) to (4) and other components are the same asin the above description of the colored photosensitive resincomposition.

(Slit Nozzle)

The coating film can be formed by coating the colored photosensitiveresin composition of the invention by a known coating method and dryingthe colored photosensitive resin composition. In a preferableembodiment, the colored photosensitive resin composition is coated byusing a slit nozzle having a slit at a portion through which the coatingliquid is discharged. Specifically, preferable are slit nozzles and slitcoaters described in JP-A No. 2004-89851, JP-A No. 2004-17043, JP-A No.2003-170098, JP-A No. 2003-164787, JP-A No. 2003-10767, JP-A No.2002-79163, and JP-A No. 2001-310147, the disclosures of which areincorporated herein by reference.

<Photosensitive Resin Transfer Material>

Next, the photosensitive resin transfer material of the invention willbe described.

The photosensitive resin transfer material of the invention ispreferably formed by using a composite film, similarly to thephotosensitive resin transfer material described in JP-A No. 5-72724,the disclosure of which is incorporated herein by reference. Thestructure of the composite film may be, for example, a lamination inwhich a temporary support, a thermoplastic resin layer, an intermediatelayer, a photosensitive resin layer, and a protective film are disposedin this order.

The photosensitive resin layer of the photosensitive resin transfermaterial of the invention is formed by using the aforementioned coloredphotosensitive resin composition of the invention.

(Temporary Support)

The temporary support is a flexible support which does not deform,shrink, or elongate remarkably even under pressure, or under pressureand heat. Examples of such a temporary support include a polyethyleneterephthalate film, a cellulose triacetate film, a polystyrene film, anda polycarbonate film. Among them, a biaxially-stretched polystyreneterephthalate film is particularly preferable.

(Thermoplastic Resin Layer)

The substance used in the thermoplastic resin layer is preferably anorganic polymer substance described in JP-A No. 5-72724 (the disclosureof which is incorporated herein by reference). The substance is morepreferably an organic polymer substance having a softening point ofabout 80° C. or lower according to the Vicat method (specifically, themethod of measuring a polymer softening point according to AmericanMaterial Test Method ASTMD1235, which is incorporated herein byreference). Specifically, the substance may be an organic polymer, andexamples thereof include: a polyolefin such as polyethylene orpolypropylene; an ethylene copolymer such as a copolymer of ethylene andvinyl acetate or a saponified product thereof; a copolymer of ethyleneand acrylic acid ester or a saponified product thereof; polyvinylchloride; a vinyl chloride copolymer such as a copolymer of vinylchloride and vinyl acetate or a saponified product thereof;polyvinylidene chloride; a vinylidene chloride copolymer; polystyrene; astyrene copolymer such as a copolymer of styrene and (meth)acrylic acidester or a saponified product thereof; polyvinyl toluene; a vinyltoluenecopolymer such as a copolymer of vinyltoluene and (meth)acrylic acidester or a saponified product thereof; poly(meth)acrylic acid ester; a(meth)acrylic acid ester copolymer such as a copolymer of butyl(meth)acrylate and vinyl acetate; and a polyamide resin such as a vinylacetate copolymer nylon, a copolymerized nylon, N-alkoxymethylatednylon, and N-dimethylaminated nylon.

(Intermediate Layer)

In the photosensitive resin transfer material of the invention, it ispreferable to provide an intermediate layer so as to prevent mixing ofcomponents during application of a plurality of coating layers andduring storage after the application. The intermediate layer ispreferably an oxygen blocking film having oxygen blocking functiondescribed as “a separating layer” in JP-A No. 5-72724, the disclosure ofwhich is incorporated herein by reference. By using such an oxygenblocking film, the exposure sensitivity is heightened, the time load ofthe exposing machine is decreased, and the productivity is improved.

The oxygen blocking film is preferably a film with a low oxygenpermeability which is dispersible or dissolvable in water or an aqueousalkaline solution. Such a film may be properly selected from knownoxygen blocking films. Among them, a combination of polyvinyl alcoholand polyvinylpyrrolidone is particularly preferable.

(Protective Film)

It is preferable to provide a protective film on a photosensitive resinlayer in order to protect the photosensitive resin layer from pollutionor damage at storage. The protective layer may be thin. The protectivefilm may comprise a material which is the same as or similar to that ofthe temporary support. The protective film should be able to be easilyseparated from the photosensitive resin layer. The protective filmmaterial may be, for example, silicone paper, polyolefin sheet orpolytetrafluoroethylene sheet.

(Method for Preparing Photosensitive Resin Transfer Material)

The photosensitive resin transfer material of the invention can beprepared by: coating a temporary support with a coating liquid (coatingliquid for thermoplastic resin layer) in which additives for athermoplastic resin layer are dissolved and drying the coating liquid toform a thermoplastic resin layer; and then coating the thermoplasticresin layer with a coating liquid for an intermediate layer containing asolvent which does not dissolve the thermoplastic resin layer, anddrying the coating liquid for an intermediate layer; and then, coatingthe intermediate layer with a coating liquid for a photosensitive resinlayer containing a solvent which does not dissolve the intermediatelayer, and drying the coating liquid for a photosensitive resin layer.

In another embodiment, the photosensitive resin transfer material isprepared by: preparing a sheet in which a thermoplastic resin layer andan intermediate layer are disposed on a temporary support, and a sheetin which a photosensitive resin layer is disposed on a protective film;and adhering the sheets to each other such that the intermediate layerand the photosensitive resin layer contact each other. In anotherembodiment, the photosensitive resin transfer material is prepared by:preparing a sheet in which a thermoplastic resin layer is disposed on atemporary support, and a sheet in which a photosensitive resin layer andan intermediate layer are disposed on a protective film; and adheringthe sheets to each other such that the thermoplastic resin layer and theintermediate layer contact each other.

In the photosensitive resin transfer material of the invention, thethickness of the photosensitive resin layer is preferably 1.0 to 5.0 μm,more preferably 1.0 to 4.0 μm, particularly preferably 1.0 to 3.0 μm.

In general, the thickness of the temporary support is preferably 15 to100 μm, the thickness of the thermoplastic resin layer is preferably 2to 30 μm, the thickness of the intermediate layer is preferably 0.5 to3.0 μm, and the thickness of the protective film is preferably 4 to 40μm. However, the thicknesses of respective layers are not limited to theabove range.

Coating operation in the above methods may be performed by a knowncoating apparatus. In the invention, it is preferable to conduct thecoating operation with the coating apparatus (slit coater) using a slitnozzle described in the above description of the coating film of acolored photosensitive resin composition. Preferable examples of theslit coater are also as described above.

<Color Filter and Method for Producing Color Filter>

(Photosensitive Resin Layer)

In the color filter of the invention: the red (R) photosensitive resinlayer comprises the colored photosensitive resin composition containingC.I.P.R.254 and C.I.P.R.177 as the coloring agents or the coating filmof the colored photosensitive resin composition containing C.I.P.R.254and C.I.P.R.177 as the coloring agents; the green (G) photosensitiveresin layer comprises the colored photosensitive resin compositioncontaining C.I.P.G36 and C.I.P.Y150 as the coloring agents or thecoating film of the colored photosensitive resin composition containingC.I.P.G36 and C.I.P.Y150 as the coloring agents; and the blue (B)photosensitive resin layer comprises the colored photosensitive resincomposition containing C.I.P.B.15:6 and C.I.P.V.23 as the coloringagents or the coating film of the colored photosensitive resincomposition containing C.I.P.B.15:6 and C.I.P.V.23 as the coloringagents.

The color filter of the invention having the above features achieves asuperior chromaticity under F10 light source at 2-degree viewing angle;particularly, even when used in a large screen liquid crystal displaydevice, the color filter of the invention realizes high color purity.

In the color filter of the invention, the difference (ΔE) between thechromaticity of the red (R) photosensitive resin layer measured under aF10 light source and the target chromaticity for red shown in Table 1,the difference (ΔE) between the chromaticity of the green (G)photosensitive resin layer measured under a F10 light source and thetarget chromaticity for green shown in Table 1, the difference (ΔE)between the chromaticity of the blue (B) photosensitive resin layermeasured under a F10 light source and the target chromaticity for blueshown in Table 1, are each preferably 5 or smaller, more preferably 3 orsmaller, still more preferably 2 or smaller.

Herein, chromaticity in the invention is measured by a microscopicspectrophotometer (OSP100 or 200 manufactured by Olympus Optics) andexpressed in terms of xyY values of the xyz color system obtained bycalculation as a result under an F10 light source at 2-degree viewingangle. In addition, the difference from the target chromaticity isexpressed in terms of a color difference of a La*b* color system. TABLE1 x y Y R 0.656 0.336 21.4 G 0.293 0.634 52.1 B 0.146 0.088 6.90

The color filter of the invention can be produced by a known method suchas a method of repeating, until the layers of the respective colors areprovided, the process comprising: forming a photosensitive resin layeron a substrate; and exposing and developing the photosensitive resinlayer. Black matrix may be introduced so as to partition the colorfilter into sections, in accordance with the necessity.

In the above production method, formation of the photosensitive resinlayer on a substrate may be conducted, for example by (a) applying therespective colored photosensitive resin compositions by a known coatingdevice or by (b) using the photosensitive resin transfer material so asto adhere the photosensitive resin layer by a laminator.

(a) Application by Coating Device

A known coating apparatus may be used for applying a coloredphotosensitive resin composition in the production method of the colorfilter of the invention. The slit-coater explained in the abovedescription of the coating film of a colored photosensitive resincomposition is particularly preferable. Preferable examples of the slitcoater are also as described above. When the photosensitive resin layeris formed by coating, its film thickness is preferably 1.0 to 3.0 μm,more preferably 1.0 to 2.5 μm, still more preferably 1.0 to 2.0 μm.

(b) Adhering by Laminator

Using the photosensitive resin transfer material of the invention, thephotosensitive resin layer formed in the film shape may be adhered tothe substrate described later by a heated and/or pressurized roller orflat plate by pressure adhesion or heat pressure adhesion. Specifically,laminators and laminating methods described in the following documentsmay be used: JP-A No. 7-110575, JP-A No. 11-77942, JP-A No. 2000-334836,and JP-A No. 2002-148794, the disclosures of which are incorporatedherein by reference. From the viewpoint of suppression of contamination,it is preferable to use the method described in JP-A No. 7-110575. Whena photosensitive resin layer is provided by the photosensitive resintransfer material of the invention, the preferable range of the filmthickness of the photosensitive resin layer is the same as thepreferable range of the film thickness described in the abovedescription of the photosensitive resin transfer material.

(Substrate)

In the invention, the substrate on which a color filter is to be formedmay be, for example, a transparent substrate, and examples thereofinclude known glass plates such as a soda glass plate having a siliconoxide film on its surface, a low-expansion glass, a non-alkali glass,and a quartz glass plate, and a plastic film.

By subjecting the substrate to a coupling treatment in advance, adhesionof the substrate to the colored photosensitive resin composition or thephotosensitive resin transfer material can be improved. The methoddescribed in JP-A No. 2000-39033 (the disclosure of which isincorporated herein by reference) is preferable as the couplingtreatment. The thickness of the substrate is not particularly limited,and is preferably 700 to 1200 μm in general.

(Oxygen Blocking Film)

In the color filter of the invention, when the photosensitive resinlayer is formed by application of the colored photosensitive resincomposition, an oxygen blocking film may be further provided on thephotosensitive resin layer, whereby the exposure sensitivity can beimproved. The oxygen blocking film may be the same as described in theabove explanation of the intermediate layer of the photosensitive resintransfer material. The thickness of the oxygen blocking film is notparticularly limited, and is preferably 0.5 to 3.0 μm in general.

(Exposure and Development)

The color filter of the invention can be obtained by repeating, untilthe resin layers of the respective colors are provided, the processcomprising: arranging a predetermined mask over the photosensitive resinlayer formed on the substrate; exposing the photosensitive resin layerto light from above the mask which has passed through the mask, thethermoplastic resin layer and the intermediate layer, and thendeveloping the photosensitive resin layer with a developer.

The light source for the exposure can be suitably selected from lightsources capable of emitting lights within the wavelength region (e.g.365 nm, 405 nm, etc.) capable of curing the photosensitive resin layer.Specific examples thereof include an ultrahigh pressure mercury lamp, ahigh pressure mercury lamp, and a metal halide lamp. The exposure amountis usually about 5 to 200 mJ/cm², preferably about 10 to 100 mJ/cm².

The developer is not particularly limited, and may be a known developersuch as the developer described in JP-A No. 5-72724, the disclosure ofwhich is incorporated herein by reference. The developer is preferably adeveloper capable of dissolving the photosensitive resin layer duringdevelopment; for example, a developer containing a compound with a pKaof 7 to 13 at a concentration of 0.05 to 5 mol/L is preferable. Thedeveloper may include a small amount of an organic solvent miscible withwater.

Examples of the organic solvent miscible with water include methanol,ethanol, 2-propanol, 1-propanol, butanol, diacetonealcohol, ethyleneglycol monomethyl ether, ethylene glycol monoethyl ether, ethyleneglycol mono-n-butyl ether, benzyl alcohol, acetone, methyl ethyl ketone,cyclohexanone, ε-caprolactone, γ-butyrolactone, dimethylformamide,dimethylacetamide, hexamethylphosphoramide, ethyl lactate, methyllactate, ε-caprolactam, and n-methylpyrrolidone. The concentration ofthe organic solvent is preferably 0.1% by mass to 30% by mass.

A known surfactant may be further added to the developer. Theconcentration of the surfactant is preferably 0.01% by mass to 10% bymass.

The developing method may be a known method such as paddle development,shower development, shower & spin development, or dip development.

In the shower development, the developer is provided onto thephotosensitive resin layer after exposure with a shower, so that theuncured portion is removed. It is preferable to provide an alkalinesolution having poor ability to dissolve the photosensitive resin layerby using a shower before development, so as to remove the thermoplasticresin layer and the intermediate layer. Further, it is preferable toprovide a cleaner by using a shower after development while rubbing thesurface with a brush or the like to remove the residue.

The liquid temperature of the developer is preferably 20° C. to 40° C.,and the pH of the developer is preferably 8 to 13.

In an embodiment of the production of the color filter of the invention,the colored photosensitive resin composition for forming a color filterare stacked to form a base, a transparent electrode is formed thereon,and protrusions for split-orientation is further provided thereon toform a spacer, as described in JP-A No. 11-248921 and Japanese PatentNo. 3255107, the disclosures of which are incorporated herein byreference. This embodiment is preferable from the viewpoint of reductionof the cost. The split-orientation refers to a state in which there are,within the same pixel, two or more regions (domains) with differentorientations of the liquid-crystal molecules.

When the colored photosensitive resin compositions are stacked bysuccessive coating operations, the film thickness becomes smaller inevery overlaying owing to the leveling of the coating liquid. For thisreason, it is preferable to stack the four colors of K(black), R, G andB and to provide protrusions for split-orientation thereon. On the otherhand, when the transfer material having a thermoplastic resin layer isused, it is preferable to stack two or three colors since thethicknesses are maintained constant.

In order to prevent deformation of the photosensitive resin layer uponlamination by overlaying the transfer material and to maintain aconstant thickness, the size of the base is preferably 25 μm or larger,more preferably 30 μm or larger.

<Liquid Crystal Display Device>

The liquid crystal display device of the invention uses the color filterof the invention having better chromaticity under an F10 light source at2-degree viewing angle, thereby realizing high color purity andeffectively preventing the coating unevenness (color unevenness causedby variation in film thickness). The liquid crystal display device ofthe invention can be suitably used also as a large screen liquid crystaldisplay device such as a display for a notebook computer and atelevision monitor.

EXAMPLES

The present invention will be explained in more detail using Examples.However, the invention is not limited to these Examples. Unlessotherwise indicated, hereinafter, “part”, “%” and “molecular weight”indicate “part by mass”, “% by mass” and “weight average molecularweight”, respectively.

Example 1

[Production of Color Filter (Production by Application Using SlitNozzle)]

-Formation of Black (K) Image-

A non-alkali glass substrate was washed by a UV washing device, thenbrush-washed with a cleaner, and then subjected to ultrasonic washingwith ultrapure water. The substrate was heat-treated at 120° C. for 3minutes to stabilize the surface state.

The glass substrate was cooled and its temperature was adjusted to 23°C. Then, the substrate was coated with a colored photosensitive resincomposition K1 having a composition shown in the following Table 2 by acoater for a glass substrate (trade name: MH-1600 manufactured by FASJapan) having a slit nozzle. Subsequently, a part of the solvent wasremoved by drying with a VCD (vacuum drying apparatus; manufactured byTokyo Ohka Kogyo Co., Ltd.) for 30 seconds to eliminate the fluidity ofthe coating layer, then unnecessary coating liquid around the substratewas removed by an EBR (Edge Bead Remover), and the glass substrate withthe coating layer was pre-baked at 120° C. for 3 minutes to give aphotosensitive resin layer K1 having a thickness of 2.4 μm.

Using a proximity-type exposure machine having a ultrahigh pressuremercury lump (manufactured by Hitachi High-Tech Electronics EngineeringCo., Ltd.), the substrate was pattern-exposed at an exposure of 300mJ/cm² with a distance of 200 μm between the photosensitive resin layerand the surface of an exposing mask (quartz exposure mask having animage pattern) while allowing the substrate and the mask to standstraight.

Then, pure water was sprayed through a shower nozzle to uniformlymoisten the surface of the photosensitive resin layer K1, and showerdeveloping was performed at 23° C. for 80 seconds with a KOH-baseddeveloper (containing KOH and a nonionic surfactant, trade name: CDK-1,manufactured by Fuji Film Electronic Materials Co., Ltd.) at a flatnozzle pressure of 0.04 MPa to obtain a patterning image. Subsequently,ultrapure water was sprayed through an ultrahigh pressure washing nozzleat a pressure of 9.8 MPa to remove the residue, to obtain a black (K)image. Subsequently, the substrate having the black image thereon washeat-treated at 220° C. for 30 minutes.

Formation of Red (R) Pixels

Using a colored photosensitive resin composition R1 having a compositiondescribed in Table 3 below, heat-treated R pixels were formed on thesubstrate having the K image formed thereon, in the same manner as theformation of the black (K) image.

The thickness of the photosensitive resin layer R1, and the coatingamounts of the pigments (C.I.P.R.254 and C.I.P.R.177) are shown in Table6.

-Formation of Green (G) Pixels-

Using a colored photosensitive resin composition G1 having a compositiondescribed in Table 4 below, heat treated G pixels were formed on thesubstrate having the K image and R pixels formed thereon, in the samemanner as the formation of the black (K) image.

The thickness of the photosensitive resin layer G1, and the coatingamounts of the pigments (C.I.P.G36 and C.I.P.Y150) are shown in Table 7.

-Formation of Blue (B) Pixels-

Using a colored photosensitive resin composition B1 having a compositiondescribed in Table 5 below, heat-treated B pixels were formed on thesubstrate having the K image, the R pixels, and the G pixels formedthereon, in the same manner as the formation of the black (K) image, sothat a desired color filter was obtained.

The thickness of the photosensitive resin layer B1, and the coatingamounts of the pigments (C.I.P.B.15:6 and C.I.P.V.23) are shown in Table8. TABLE 2 Colored photosensitive resin composition K1 K pigmentdispersion 1 25 (carbon black) Propylene glycol monomethyl ether acetate8.0 Methyl ethyl ketone 53 Binder 2 9.1 Hydroquinone monomethyl ether0.002 DPHA liquid 4.22,4-Bis(trichloromethyl)-6-[4′-(N,N-bisethoxycarbonylmethyl)- 0.163′-bromophenyl]-s-triazine Surfactant 1 0.044(Unit: part)

TABLE 3 Example Comparative Example 1 2 3 4 5 6 7 8 9 10 1 2 3 Coloredphotosensitive R1 R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 resincomposition R pigment dispersion 1 40.0 42.0 44.0 46.0 48.0 40.0 42.044.0 46.0 48.0 38.0 50.0 50.0 (C.I.P.R.254) R pigment dispersion 2 4.54.7 5.0 5.2 5.5 4.5 4.7 5.0 5.2 5.5 4.3 5.7 5.7 (C.I.P.R.177) Propyleneglycol 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 monomethylether acetate Methyl ethyl ketone 37 37 37 37 37 37 37 37 37 37 37 37 37Binder-1 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 DPHA liquid3.8 3.8 3.8 3.6 3.8 3.8 3.8 3.8 3.8 3.8 3.8 3.8 3.8 2-trichloromethyl-5-0.12 0.12 0.12 0.12 0.12 0.17 0.17 0.17 0.17 0.17 0.17 0.17 0.17(p-styrylstyryl)-1,3,4- oxadiazole 2,4-Bis(trichloromethyl)- 0.05 0.050.05 0.05 0.05 — — — — — — 0.05 0.05 6-[4′-(N,N- bisethoxycarbonyl-methyl)-3′- bromophenyl]-s-triazine Phenothiazine 0.010 0.010 0.0100.010 0.010 0.009 0.009 0.009 0.009 0.009 0.009 0.009 0.009 Surfactant 10.06 0.06 0.06 0.06 0.03 0.06 0.06 0.06 0.06 0.06 0.06 0.06 —(Unit: part)

TABLE 4 Example Comparative Example 1 2 3 4 5 6 7 8 9 10 1 2 3 Coloredphotosensitive G1 G2 G3 G4 G5 G6 G7 G8 G9 G10 G11 G12 G13 resincomposition G pigment dispersion 1 28.4 26.1 23.7 21.3 19.0 28.4 26.123.7 21.3 19.0 29.6 16.6 16.6 (C.I.P.G.36) Y pigment dispersion 1 15.013.8 12.5 11.3 10.0 15.0 13.8 12.5 11.3 10.0 15.6 8.8 8.8 (C.I.P.Y.150)Propylene glycol 29.1 29.1 29.1 29.1 29.1 29.1 29.1 29.1 29.1 29.1 29.129.1 29.1 monomethyl ether acetate Methyl ethyl ketone 26 26 26 26 26 2626 26 26 26 26 26 26 Cyclohexanone 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.31.3 1.3 1.3 1.3 Binder-2 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.52.5 DPHA liquid 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.52-trichloromethyl-5- 0.12 0.12 0.12 0.12 0.12 0.17 0.17 0.17 0.17 0.170.12 0.12 0.12 (p-styrylstyryl)-1,3,4- oxadiazole2,4-Bis(trichloromethyl)- 0.05 0.05 0.05 0.05 0.05 — — — — — — 0.05 0.056-[4′-(N,N- bisethoxycarbonyl- methyl)-3′- bromophenyl]-s-triazinePhenothiazine 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.0050.005 0.005 0.005 0.005 Surfactant 1 0.07 0.07 0.07 0.07 0.07 0.07 0.070.07 0.07 0.07 0.07 0.07 —(Unit: part)

TABLE 5 Comparative Example Example 1 2 3 4 5 6 7 8 9 10 1 2 3 Coloredphotosensitive resin B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 B13composition B pigment dispersion 1 8.6 8.4 8.0 7.6 7.4 8.6 8.4 8.0 7.67.4 8.8 7.2 7.2 (C.I.P.B.15:6) B pigment dispersion 2 15.0 14.7 14.013.3 13.0 15.0 14.7 14.0 13.3 13.0 15.4 12.6 12.6 (C.I.P.B.15:6C.I.P.V.23) Propylene glycol monomethyl ether 28 28 28 28 28 28 28 28 2828 28 28 28 acetate Methyl ethyl ketone 26 26 26 26 26 26 26 26 26 26 2626 26 Binder-3 17.2 17.2 17.2 17.2 17.2 17.2 17.2 17.2 17.2 17.2 17.217.2 17.2 DPHA liquid 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.04.0 2-trichloromethyl-5-(p-styrylstyryl)- 0.14 0.14 0.14 0.14 0.14 0.160.16 0.16 0.16 0.16 0.16 0.16 0.16 1,3,4-oxadiazole2,4-Bis(trichloromethyl)-6-[4′-(N,N- 0.02 0.02 0.02 0.02 0.02 — — — — — —0.02 0.02 bisethoxycarbonylmethyl)-3′- bromophenyl]-s-triazinePhenothiazine 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.020.02 0.02 Surfactant 1 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.060.06 0.06 —(Unit: part)

Herein, preparation of the colored photosensitive resin compositions K1,R1, G1 and B1 described in the above Tables 2 to 5 will be explained.

The colored photosensitive resin composition K1 was obtained by:measuring off the K pigment dispersion 1 and propylene glycol monomethylether acetate respectively in the amounts shown in Table 2, then mixingthem at a temperature of 24° C.(±2° C.) and stirring the mixture at 150RPM for 10 minutes, then measuring off methyl ethyl ketone, the binder2, hydroquinone monomethyl ether, the DPHA liquid,2,4-bis(trichloromethyl)-6-[4′-(N,N-bisethoxycarbonylmethyl)-3′-bromophenyl]-s-triazine,and the surfactant 1 respectively in the amounts shown in Table 2, thenadding them to the above mixture in this order at a temperature of 25°C.(±), and then stirring the resultant mixture at 150 RPM at atemperature of 40° C.(±2° C.) for 30 minutes.

In the composition shown in Table 2, the K pigment dispersion 1 had thefollowing composition: Carbon black  13.1 parts Dispersant (compound 1shown below)  0.65 part Polymer (random copolymer of benzyl methacrylateand methacrylic  6.72 parts acid (benzyl methacrylate/methacrylic acid =72/28 by mol), molecular weight: 37,000) Propylene glycol monomethylether acetate 79.53 parts

the binder 2 had the following composition: Polymer (random copolymer ofbenzyl methacrylate and 27 parts methacrylic acid (benzylmethacrylate/methacrylic acid = 78/22 by mol), molecular weight: 38,000)Propylene glycol monomethyl ether acetate 73 parts

the DPHA liquid had the following composition: Dipentaerythritolhexaacrylate (containing 500 ppm of 76 parts polymerization inhibitorMEHQ; manufactured by Nippon Kayaku Co., Ltd., trade name: KAYARAD DPHA)Propylene glycol monomethyl ether acetate 24 parts

the surfactant 1 had the following composition: Polymer structure 1shown below 30 parts Methyl ethyl ketone 70 parts Polymer Structure 1

(n = 6, x = 55, y = 5, Mw = 33940, Mw/Mn = 2.55 PO: propylene oxide, EO:ethylene oxide)

The colored photosensitive resin composition R1 was obtained by:measuring off the R pigment dispersion 1, the R pigment dispersion 2,and propylene glycol monomethyl ether acetate respectively in theamounts shown in Table 3, then mixing them at a temperature of 24°C.(±2° C.) and stirring the mixture at 150 RPm for 10 minutes, thenmeasuring off methyl ethyl ketone, the binder 1, the DPHA liquid,2-trichloromethyl-5-(p-styrylstyryl)-1,3,4-oxadiazole,2,4-bis(trichlormethyl)-6-[4′-(N,N-bisethoxycarbonylmethyl)-3′-bromophenyl]-s-triazine,and phenothiazine respectively in the amounts shown in Table 3, thenadding them to the above mixture in this order at a temperature of 24°C.(±2° C.) and then stirring the resultant mixture at 150 RPM for 30minutes, then measuring off the surfactant 1 in the amount shown inTable 3, then adding the surfactant 1 to the mixture at a temperature of24° C.(±2° C.), then stirring the resultant mixture at 30 RPM for 5minutes, and then filtering the mixture with a nylon mesh #200.

In the composition shown in Table 3,

the R pigment dispersion 1 had the following composition: C.I.P.R.254 8parts Dispersant (compound 1 shown above) 0.8 part Polymer (randomcopolymer of benzyl methacrylate and 8 parts methacrylic acid (benzylmethacrylate/methacrylic acid = 72/28 by mol), molecular weight: 30,000)Propylene glycol monomethyl ether acetate 83 parts

the R pigment dispersion 2 had the following composition: C.I.P.R.177 18parts Polymer (random copolymer of benzyl methacrylate and 12 partsmethacrylic acid (benzyl methacrylate/methacrylic acid = 72/28 by mol),molecular weight: 30,000) Propylene glycol monomethyl ether acetate 70parts

the binder 1 had the following composition: a polymer (a randomcopolymer of benzyl methacrylate, 27 parts methacrylic acid, and methylmethacrylate (benzyl methacrylate:methacrylic acid:methyl methacrylate =38:25:37 by mol), molecular weight: 40,000) propyleneglycol monomethylether acetate 73 parts

The colored photosensitive resin composition G 1 was obtained bymeasuring off the G pigment dispersion 1, the Y pigment dispersion 1,and propylene glycol monomethyl ether acetate respectively in theamounts shown in Table 4, then mixing them at a temperature of 24°C.(±2° C.) and stirring the mixture at 150 RPM for 10 minutes, thenmeasuring off methyl ethyl ketone, cyclohexanone, the binder 2, the DPHAliquid, 2-trichloromethyl-5-(p-styrylstyryl)- 1,3,4-oxadiazole,2,4-bis(trichloromethyl)-6-[4′-(N,N-bisethoxycarbonylmethyl)-3′-bromophenyl]-s-triazine,and phenothiazine respectively in the amounts shown in Table 4, thenadding them to the above mixture in this order at a temperature of 24°C.(±2° C.), then stirring the resultant mixture at 150 RPM for 30minutes, then measuring off the surfactant 1 in the amount shown inTable 4, then adding the surfactant 1 to the mixture at a temperature of24° C.(±2° C.), then stirring the resultant mixture at 30 RPM for 5minutes, and then filtering the mixture with a nylon mesh #200.

In the composition shown in Table 4,

the G pigment dispersion 1 had the following composition: C.I.P.G.36 18parts Polymer (random copolymer of benzyl methacrylate and 12 partsmethacrylic acid (benzyl methacrylate/methacrylic acid = 72/28 by mol),molecular weight: 38,000) Cyclohexanone 35 parts Propylene glycolmonomethyl ethyl acetate 35 parts

the Y pigment dispersion 1 was CF Yellow EX3393 manufactured by MikuniShikiso Co., Ltd.

The colored photosensitive resin composition B1 was obtained by:measuring off the B pigment dispersion 1, the B pigment dispersion 2,and propylene glycol monomethyl ether acetate respectively in theamounts shown in Table 5, then mixing them a temperature of 24° C.(±2°C.) and stirring the mixture at 150 RPM for 10 minutes, then measuringoff methyl ethyl ketone, the binder 3, the DPHA liquid,2-trichloromethyl-5-(p-styrylstyryl)-1,3,4-oxadiazole, and2,4-bis(trichloromethyl)-6-[4′-(N,N-bisethoxycarbonylmethyl)-3′-bromophenyl]-s-triazine,and phenothiazine respectively in the amounts shown in Table 5, thenadding them to the above mixture in this order at a temperature of 25°C.(±2° C.), then stirring the mixture at 150 RPM at a temperature of 40°C.(±2° C.) for 30 minutes, then measuring off the surfactant 1 in theamount shown in Table 5, then adding the surfactant 1 to the mixture ata temperature of 24° C.(±2° C.), then stirring the mixture at 30 RPM for5 minutes, and then filtering the mixture with a nylon mesh #200.

In the composition shown in Table 5,

the B pigment dispersion 1 was CF Blue EX3357 manufactured by MikuniShikiso Co., Ltd.

the pigment dispersion 2 was CF Blue EX3383 manufactured by MikuniShikiso Co, Ltd.

the binder 3 had the following composition: Polymer (random copolymer ofbenzyl methacrylate-methacrylic 27 parts acid-methyl methacrylate(benzyl methacrylate:methacrylic acid:methyl methacrylate = 36/22/42 bymol), molecular weight: 38,000) Propylene glycol monomethyl etheracetate 73 parts

Examples 2 to 10 and Comparative Examples 1 to 3

Color filters were obtained in the same manner as in Example 1, exceptthat the compositions of the colored photosensitive resin compositionR1, G1 or B1 used in Example 1 were replaced by compositions of coloredphotosensitive resin compositions R2 to R13, G2 to G13 or B2 to B13shown in Tables 3 to 5, respectively.

The thicknesses of the respective photosensitive resin layers of R, Gand B, and the coating amounts of the respective pigments are shown inTables 6 to 8.

[Evaluation]

-Measurement of Chromaticity-

Chromaticity of the color filters obtained above was measured with amicroscopic photometer (trade name: OSP100 manufactured by OlympusOptics) at a pinhole diameter of 5 μm, and calculated as the resultunder an F10 light source with the 2-degree viewing angle. The results(xyY values, and difference (ΔE) from the target chromaticity) are shownin Tables 6 to 8.

-Coating Unevenness-

Substrates immediately after coating of the respective coloredphotosensitive resin compositions of R, G and B were irradiated with alight from an oblique direction emitted by a Na lamp in a dark chamber,and observed with the naked eye and under a magnifying glass, to confirmwhether unevenness occurred or not.

-Display Unevenness-

After completion of the patterning, the substrates with pixels wereirradiated with a light from an oblique direction emitted by a Na lampin a dark chamber, and observed with the naked eye and under amagnifying glass, to confirm whether unevenness occurred or not.

-Overall Evaluation-

From the above evaluations, overall evaluation of the color filters wasperformed under the following criteria.

-   A: The ΔE value, coating unevenness, and display unevenness are all    superior.-   B: Although the ΔE value was better, slight coating unevenness or    occurrence of display unevenness is observed.-   C: At least one of the ΔE value, coating unevenness, and display    unevenness is markedly inferior.

The above evaluation results are shown in Tables 6 to 8. TABLE 6 ExampleComparative Example 1 2 3 4 5 6 7 8 9 10 1 2 3 Colored photosensitive R1R2 R3 R4 R5 R6 R7 R8 R9 R10 R11 R12 R13 resin composition Photosensitiveresin layer 1.60 1.60 1.60 1.60 1.60 1.60 1.60 1.60 1.60 1.60 1.60 1.601.60 thickness (μm) Pigment coating amount 1.00 1.05 1.10 1.15 1.20 1.001.05 1.10 1.15 1.20 0.95 1.25 1.25 (g/m²) C.I.P.R.254 0.80 0.84 088 0.920.96 0.80 0.84 0.88 0.92 0.96 0.76 1.00 1.00 Coating amount (g/m²)C.I.P.R.177 0.20 0.21 0.22 0.23 0.24 0.20 0.21 0.22 0.23 0.24 0.19 0.250.25 Coating amount (g/m²) x 0.652 0.654 0.656 0.658 0.659 0.652 0.6540.656 0.658 0.659 0.650 0.661 0.661 y 0.335 0.336 0.336 0.335 0.3350.335 0.336 0.336 0.335 0.335 0.334 0.335 0.335 Y 22.1 21.8 21.4 21.120.7 22.1 21.8 21.4 21.1 20.7 22.3 20.4 20.4 ΔE 4.8 2.3 0 2.0 3.9 4.82.3 0 2.0 3.9 8.4 6.5 6.5 Coating unevenness Not Not Not Not Not Not NotNot Not Not Not Not Observ- observ- observ- observ- observ- observ-observ- observ- observ- observ- observ- observ- observ- able able ableable able able able able able able able able able Display unevenness NotNot Not Not Not Slightly Slightly Slightly Slightly Slightly SlightlyNot Observ- observ- observ- observ- observ- observ- observ- observ-observ- observ- observ- observ- observ- able able able able able ableable able able able able able able Evaluation A A A A A B B B B B C C C(Unit: part)

TABLE 7 Example Comparative Example 1 2 3 4 5 6 7 8 9 10 1 2 3 Coloredphotosensitive G1 G2 G3 G4 G5 G6 G7 G8 G9 G10 G11 G12 G13 resincomposition Photosensitive resin layer 1.60 1.60 1.60 1.60 1.60 1.601.60 1.60 1.60 1.60 1.60 1.60 1.60 thickness (μm) Pigment coating amount1.92 1.76 1.60 1.44 1.28 1.92 1.76 1.60 1.44 1.28 2.00 1.12 1.12 (g/m²)C.I.P.G.36 1.34 1.23 1.12 1.01 0.90 1.34 1.23 1.12 1.01 0.90 1.40 0.780.78 Coating amount (g/m²) C.I.P.Y.150 0.58 0.53 0.48 0.43 0.38 0.580.53 0.48 0.43 0.38 0.60 0.34 0.34 Coating amount (g/m²) x 0.284 0.2880.293 0.297 0.301 0.284 0.288 0.293 0.297 0.301 0.280 0.303 0.303 y0.649 0.641 0.634 0.626 0.618 0.649 0.641 0.634 0.626 0.618 0.656 0.6140.614 Y 47.7 50.0 52.1 54.4 56.6 47.7 50.0 52.1 54.4 56.6 45.7 57.8 57.8ΔE 4.0 1.8 0 2.3 4.6 4.0 1.8 0 2.3 4.6 5.7 5.8 5.8 Coating unevennessNot Not Not Not Not Not Not Not Not Not Not Not Observ- observ- observ-observ- observ- observ- observ- observ- observ- observ- observ- observ-observ- able able able able able able able able able able able able ableDisplay unevenness Not Not Not Not Not Slightly Slightly SlightlySlightly Slightly Slightly Not Observ- observ- observ- observ- observ-observ- observ- observ- observ- observ- observ- observ- observ- ableable able able able able able able able able able able able Evaluation AA A A A B B B B B C C C(Unit: part)

TABLE 8 Example Comparative Example 1 2 3 4 5 6 7 8 9 10 1 2 3 Coloredphotosensitive B1 B2 B3 B4 B5 B6 B7 B8 B9 B10 B11 B12 B13 resincomposition Photosensitive resin layer 1.60 1.60 1.60 1.60 1.60 1.601.60 1.60 1.60 1.60 1.60 1.60 1.60 thickness (μm) Pigment coating amount0.75 0.74 0.70 0.67 0.65 0.75 0.74 0.70 0.67 0.65 0.77 0.63 0.63 (g/m²)C.I.P.B.15:6 0.67 0.66 0.63 0.60 0.59 0.67 0.66 0.63 0.60 0.59 0.69 0.570.57 Coating amount (g/m²) C.I.P.V.23 0.075 0.074 0.070 0.067 0.0650.075 0.074 0.070 0.067 0.065 0.077 0.063 0.063 Coating amount (g/m²) x0.145 0.145 0.146 0.147 0.147 0.145 0.145 0.146 0.147 0.147 0.145 0.1470.147 y 0.082 0.084 0.088 0.092 0.094 0.082 0.084 0.088 0.092 0.0940.080 0.097 0.097 Y 6.24 6.40 6.85 7.37 7.59 6.24 6.40 6.85 7.37 7.595.92 7.86 7.86 ΔE 4.0 2.9 0 3.2 4.6 4.0 2.9 0 3.2 4.6 6.3 6.3 6.3Coating unevenness Not Not Not Not Not Not Not Not Not Not Not NotObserv- observ- observ- observ- observ- observ- observ- observ- observ-observ- observ- observ- observ- able able able able able able able ableable able able able able Display unevenness Not Not Not Not Not SlightlySlightly Slightly Slightly Slightly Slightly Not Observ- observ- observ-observ- observ- observ- observ- observ- observ- observ- observ- observ-observ- able able able able able able able able able able able able ableEvaluation A A A A A B B B B B C C C(Unit: part)Production and Evaluation of Liquid Crystal Display Device]

Liquid crystal display device was formed using the color filters ofExamples 1 to 10 and the color filters of Comparative Examples 1 to 3.It was confirmed that the liquid crystal display devices using the colorfilters of Examples shows better display property than the liquidcrystal display devices using the color filters of Comparative Examples.

Example 11

[Production of Color Filter (Production by Lamination of PhotosensitiveResin Transfer Material)]

-Production of Photosensitive Resin Transfer Material-

A thermoplastic resin layer coating liquid having the followingformulation H1 was coated on a polyethylene terephthalate film temporarysupport with a thickness of 75 μm using a slit nozzle, followed bydrying. Then, an intermediate layer coating liquid having the followingformulation P1 was coated thereon, and dried. Further, the coloredphotosensitive resin composition K1 was coated thereon and dried. Inthis way, a thermoplastic resin layer with a dry film thickness of 14.6μm, an intermediate layer with a dry film thickness of 1.6 μm, and aphotosensitive resin layer with a dry film thickness of 2.4 μm wereprovided on the temporary support. Further, a protective film(polypropylene film with a thickness of 12 μm) was adhered onto thephotosensitive resin layer by pressure.

As described above, a photosensitive resin transfer material K1 wasproduced in which the temporary support, the thermoplastic resin layer,the intermediate layer (oxygen blocking film), and the black (K)photosensitive resin layer were unified.

Formulation H1 for thermoplastic resin layer coating liquid: Methanol11.1 parts Propylene glycol monomethyl ether acetate 6.36 parts Methylethyl ketone 52.4 parts Methyl methacrylate-(2-ethylhexylacrylate)-benzyl 5.83 parts methacrylate-methacrylic acid copolymer(copolymer composition ratio (mole ratio): Methyl methacrylate/2-ethylhexyl acrylate/benzyl methacrylate/methacrylic acid =55/11.7/4.5/28.8, molecular weight = 90000, Tg: about 70° C.)Styrene-acrylic acid copolymer (copolymerization 13.6 parts compositionratio (mole ratio): Styrene/acrylic acid = 63/37, molecular weight =10000, Tg: 100° C.) Compound obtained by dehydration-condensation of 9.1parts bisphenol A with 2 equivalents of pentaethylene glycolmonomethacrylate (trade name: 2,2-bis[4-methacryloxypolyethoxy)phenyl]propane manufactured by Shin-NakamuraChemical Co., Ltd.) Surfactant 1 described above 0.54 part

Formulation P1 for intermediate layer coating liquid: PVA205 (polyvinylalcohol, manufactured by Kuraray Co., 32.2 parts Ltd., saponificationdegree = 88%, polymerization degree 550) Polyvinylpyrrolidone (tradename: K-30 manufactured by 14.9 parts ISP Japan Ltd.) Distilled water524 parts Methanol 429 parts

Photosensitive resin transfer materials R101, G101 and B101 wereproduced in the same manner as the production of the photosensitiveresin transfer material K1, except that the colored photosensitive resincomposition K1 used in production of the photosensitive resin transfermaterial K1 was replaced respectively by colored photosensitive resincompositions R101, G101 or B101 having the compositions shown in Tables9 to 11 below.

The methods for producing the colored photosensitive resin compositionsR101, G101 and B101 were similar to the methods for producing thecolored photosensitive resin compositions R1, G1 or B1, respectively.TABLE 9 Example Comparative Example 11 12 13 14 15 16 17 18 19 20 4 5 6Colored photosensitive R101 R102 R103 R104 R105 R106 R107 R108 R109 R110R111 R112 R113 resin composition R pigment dispersion 1 40.0 42.0 44.046.0 48.0 40.0 42.0 44.0 46.0 48.0 38.0 50.0 50.0 (C.I.P.R.254) Rpigment dispersion 2 4.5 4.7 5.0 5.2 5.5 4.5 4.7 5.0 5.2 5.5 4.3 5.7 5.7(C.I.P.R.177) Propylene glycol 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.6 7.67.6 7.6 7.6 monomethyl ether acetate Methyl ethyl ketone 37 37 37 37 3737 37 37 37 37 37 37 37 Binder-1 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.80.8 0.8 0.8 DPHA liquid 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.4 4.44.4 2-trichloromethyl-5- 0.14 0.14 0.14 0.14 0.14 0.20 0.20 0.20 0.200.20 0.20 0.20 0.20 (p-styrylstyryl)-1,3,4- oxadiazole2,4-Bis(trichloromethyl)- 0.06 0.06 0.06 0.06 0.06 — — — — — — 0.06 0.066-[4′-(N,N- bisethoxycarbonyl- methyl)-3′- bromophenyl]-s-triazinePhenothiazine 0.010 0.010 0.010 0.010 0.010 0.009 0.009 0.009 0.0090.009 0.009 0.009 0.009 Additive 1 0.52 0.52 0.52 0.52 0.52 0.52 0.520.52 0.52 0.52 0.52 0.52 0.52 Surfactant 1 0.06 0.06 0.06 0.06 0.03 0.060.06 0.06 0.06 0.06 0.06 0.06 —(Unit: part)

TABLE 10 Example Comparative Example 11 12 13 14 15 16 17 18 19 20 4 5 6Colored photosensitive G101 G102 G103 G104 G105 G106 G107 G108 G109 G110G111 G112 G113 resin composition G pigment dispersion 1 28.4 26.1 23.721.3 19.0 28.4 26.1 23.7 21.3 19.0 29.6 16.6 16.6 (C.I.P.G.36) Y pigmentdispersion 1 15.0 13.8 12.5 11.3 10.0 15.0 13.8 12.5 11.3 10.0 15.6 8.88.8 (C.I.P.Y.150) Propylene glycol 29.1 29.1 29.1 29.1 29.1 29.1 29.129.1 29.1 29.1 29.1 29.1 29.1 monomethyl ether acetate Methyl ethylketone 26 26 26 26 26 26 26 26 26 26 26 26 26 Cyclohexanone 1.3 1.3 1.31.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 Binder-2 3.0 3.0 3.0 3.0 3.0 3.03.0 3.0 3.0 3.0 3.0 3.0 3.0 DPHA liquid 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.34.3 4.3 4.3 4.3 4.3 2-trichloromethyl-5- 0.15 0.15 0.15 0.15 0.15 0.210.21 0.21 0.21 0.21 0.15 0.15 0.15 (p-styrylstyryl)-1,3,4- oxadiazole2,4-Bis(trichloromethyl)- 0.06 0.06 0.06 0.06 0.06 — — — — — — 0.06 0.066-[4′-(N,N- bisethoxycarbonyl- methyl)-3′- bromophenyl]-s-triazinePhenothiazine 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.0050.005 0.005 0.005 0.005 Surfactant 1 0.07 0.07 0.07 0.07 0.07 0.07 0.070.07 0.07 0.07 0.07 0.07 —(Unit: part)

TABLE 11 Comparative Example Example 11 12 13 14 15 16 17 18 19 20 4 5 6Colored photosensitive B101 B102 B103 B104 B105 B106 B107 B108 B109 B110B111 B112 B113 resin composition B pigment dispersion 1 8.6 8.4 8.0 7.67.4 8.6 8.4 8.0 7.6 7.4 8.8 7.2 7.2 (C.I.P.B.15:6) B pigment dispersion2 15.0 14.7 14.0 13.3 13.0 15.0 14.7 14.0 13.3 13.0 15.4 12.6 12.6(C.I.P.B.15:6 C.I.P.V.23) Propylene glycol 28 28 28 28 28 28 28 28 28 2828 28 28 monomethyl ether acetate Methyl ethyl ketone 26 26 26 26 26 2626 26 26 26 26 26 26 Binder-3 18.5 18.5 18.5 18.5 18.5 18.5 18.5 18.518.5 18.5 18.5 18.5 18.5 DPHA liquid 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.3 4.34.3 4.3 4.3 4.3 2-trichloromethyl-5- 0.15 0.15 0.15 0.15 0.15 0.17 0.170.17 0.17 0.17 0.17 0.17 0.17 (p-styrylstyryl)-1,3,4-oxadiazole2,4-bis(trichloromethyl)- 0.02 0.02 0.02 0.02 0.02 — — — — — — 0.02 0.026-[4′-(N,N-bisethoxycarbonyl- methyl)-3′-bromophenyl]-s- triazinePhenothiazine 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.020.02 0.02 Surfactant 1 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.060.06 0.06 —(Unit: part)

In the compositions shown in Table 9, the additive 1 was aphosphoric-ester-based special surfactant (HIPLAAD ED152 manufactured byKusumoto Chemicals Ltd.).

-Formulation of Black (K) Image-

A non-alkali glass substrate was washed with a rotating brush havingnylon hairs while a glass cleaner liquid regulated at 25° C. was sprayedby a shower for 20 seconds, then the glass substrate was washed withpure water shower. Thereafter, a silane coupling solution (a 0.3%aqueous solution of N-β(aminoethyl) γ-aminopropyltrimethoxysilane, tradename: KBM603, manufactured by Shin-Etsu Chemical Co., Ltd.) was sprayedfor 20 seconds by a shower, and the substrate was washed with a purewater shower. This substrate was heat-treated by a substrate pre-heatingapparatus at 100° C. for 2 minutes, and was supplied to the nextlaminator.

The protective film of the photosensitive resin transfer material K1 waspeeled off, and the substrate heated to 100° C. was laminated with thephotosensitive resin transfer material R101 at a rubber rollertemperature of 130° C., a linear pressure of 100 N/cm², and a conveyingrate of 2.2 m/min, using a laminator (LACMIC II type, manufactured byHitachi Industries Co., Ltd.).

After the temporary support was peeled off, the photosensitive resin waspattern-exposed by using a proximity-type exposure machine having anultrahigh pressure mercury lamp (manufactured by Hitachi High-TechElectronics Engineering Co., Ltd) at an exposure of 70 mJ/cm² with adistance of 200 μm between the photosensitive resin layer and thesurface of the exposure mask (quartz exposure mask having imagepattern), while allowing the substrate and the mask to stand straight.

Then, shower development was performed with a triethanolamine-baseddeveloper (trade name: T-PD1 manufactured by Fuji Photo Film Co., Ltd.,containing 2.5% of triethanolamine and also containing nonionicsurfactant and polypropylene-based anti-foaming agent) at 30° C. for 50seconds at a flat nozzle pressure of 0.04 MPa, so that the thermoplasticresin layer and the oxygen blocking film were removed.

Subsequently, using a sodium-carbonate-based developer (trade name:T-CD1, manufactured by Fuji Photo Film Co., Ltd., containing 0.06 mol/lof sodium bicarbonate, 0.06 mol/l of sodium carbonate, and 1% of sodiumdibutylnaphthalenesulfonate, and also containing an anionic surfactant,an anti-foaming agent, and a stabilizer), another shower developing wasperformed at 29° C. for 30 seconds under a cone-type nozzle pressure of0.15 MPa to develop the photosensitive resin layer, so that thepatterning image was obtained.

Subsequently, using a detergent (trade name: “T-SD1” (manufactured byFuji Photo Film Co., Ltd.) containing a phosphate, a silicate, anonionic surfactant, an anti-foaming agent, and a stabilizer, or tradename “T-SD2” (manufactured by Fuji Photo Film Co., Ltd.) containingsodium carbonate and a phenoxyoxyethylene-based surfactant), the residuewas removed by a shower and a rotating brush having nylon hairs at 33°C. for 20 seconds under a cone-type nozzle pressure of 0.02 MPa, so thata black (K) image was obtained. Thereafter, after the substrate wassubjected to post exposure to light of 500 mJ/cm² from the resin layerside emitted by an ultrahigh pressure mercury lamp, heat-treatment wasperformed at 220° C. for 15 minutes.

The substrate having the K image formed thereon was washed with a brushin the same manner as described above, and then washed with pure watershower, and then supplied to a substrate pre-heating apparatus withoutusing a silane coupling liquid.

-Formation of Red (R) Pixels-

Heat-treated green (R) pixels were obtained by using the photosensitiveresin transfer material R101, in the same manner as the formation of theblack (K) image with the photosensitive resin transfer material K1. Theexposure was 40 mJ/cm², and the development with thesodium-carbonate-based developer was performed at 35° C. for 35 seconds.

The thickness of the photosensitive layer R101, and the coating amountsof the pigments (C.I.P.R.254 and C.I.P.R.177) are shown in Table 12.

The substrate having the K image and the R pixels thereon was washedagain with a brush in the same manner as described above, and washedwith pure water shower, and supplied to a substrate pre-heatingapparatus without using a silane coupling liquid.

-Formation of Green (G) Pixels-

Heat-treated green (G) pixels were obtained by using the photosensitiveresin transfer material G101, in the same manner as the formation of thered (R) image with the photosensitive resin transfer material R101. Theexposure was 40 mJ/cm², and the development with thesodium-carbonate-based developer was performed at 34° C. for 45 seconds.

The thickness of the photosensitive layer G101 and the coating amountsof the pigments (C.I.P.G36 and C.I.P.Y.150) are shown in Table 13.

This substrate having the K image, the R pixels, and G pixels thereonwas washed again with a brush in the same manner as described above,then washed with pure water shower, then supplied to the substratepre-heating apparatus without using a silane coupling liquid.

-Formation of Blue (B) Pixels-

Heat-treated blue (B) pixels were obtained by using the photosensitiveresin transfer material B101 in the same manner as the formation of thered (R) image with the photosensitive resin transfer material R101. Theexposure was 30 mJ/cm², and the development with thesodium-carbonate-based developer was performed at 36° C. for 40 seconds.

The thickness of the photosensitive resin layer B101 and the coatingamounts of the pigments (C.I.P.B.15:6 and C.I.P.V.23) are shown in Table14.

This substrate having the K image, the R pixels, the G pixels, and the Bpixels thereon was baked at 240° C. for 50 minutes to obtain a colorfilter.

Example 12 to 20 and Comparative Examples 4 to 6

Color filters were obtained in the same manner as in Example 11 exceptthat the colored photosensitive resin compositions R101, G101 and B101used in Example 11 were replaced by colored photosensitive resincompositions R102 to R113, G102 to G113, and B102 to B113 having thecomposition described in Tables 9 to 11.

The thicknesses of the respective photosensitive resin layer of R, G andB, and the coating amounts of the respective pigments are shown inTables 12 to 14.

[Evaluation]

Measurement of chromaticity, observation of coating unevenness anddisplay unevenness, and overall evaluation of the color filters wereconducted by the same method and criteria as described above.

The evaluation results are shown in Tables 12 to 14. TABLE 12 ExampleComparative Example 11 12 13 14 15 16 17 18 19 20 4 5 6 Coloredphotosensitive R101 R102 R103 R104 R105 R106 R107 R108 R109 R110 R111R112 R113 resin composition Photosensitive resin layer 2.0 2.0 2.0 2.02.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 thickness (μm) Pigment coatingamount 1.00 1.05 1.10 1.15 1.20 1.00 1.05 1.10 1.15 1.20 0.95 1.25 1.25(g/m²) C.I.P.R.254 0.80 0.84 0.88 0.92 0.96 0.80 0.84 0.88 0.92 0.960.76 1.00 1.00 Coating amount (g/m²) C.I.P.R.177 0.20 0.21 0.22 0.230.24 0.20 0.21 0.22 0.23 0.24 0.19 0.25 0.25 Coating amount (g/m²) x0.652 0.654 0.656 0.658 0.659 0.652 0.654 0.656 0.658 0.659 0.650 0.6610.661 y 0.335 0.336 0.336 0.335 0.335 0.335 0.336 0.336 0.335 0.3350.334 0.335 0.335 Y 22.1 21.8 21.4 21.1 20.7 22.1 21.8 21.4 21.1 20.722.3 20.4 20.4 ΔE 4.8 2.3 0 2.0 3.9 4.8 2.3 0 2.0 3.9 8.4 6.5 6.5Coating unevenness Not Not Not Not Not Not Not Not Not Not Not NotObserv- observ- observ- observ- observ- observ- observ- observ- observ-observ- observ- observ- observ- able able able able able able able ableable able able able able Display unevenness Not Not Not Not Not SlightlySlightly Slightly Slightly Slightly Slightly Not Observ- observ- observ-observ- observ- observ- observ- observ- observ- observ- observ- observ-observ- able able able able able able able able able able able able ableEvaluation A A A A A B B B B B C C C(Unit: part)

TABLE 13 Example 11 12 13 14 15 16 17 Colored photosensitive G101 G102G103 G104 G105 G106 G107 resin composition Photosensitive resin layer2.0 2.0 2.0 2.0 2.0 2.0 2.0 thickness (μm) Pigment coating amount 1.921.76 1.60 1.44 1.28 1.00 1.05 (g/m²) C.I.P.G.36 1.34 1.23 1.12 1.01 0.900.70 0.74 Coating amount (g/m²) C.I.P.Y.150 0.58 0.53 0.48 0.43 0.380.30 0.32 Coating amount (g/m²) x 0.284 0.288 0.293 0.297 0.301 0.2840.288 y 0.649 0.641 0.634 0.626 0.618 0.649 0.641 Y 47.7 50.0 52.1 54.456.6 47.7 50.0 ΔE 4.0 1.8 0 2.3 4.6 4.0 1.8 Coating unevenness Not NotNot Not Not Not Not observable observable observable observableobservable observable observable Display unevenness Not Not Not Not NotSlightly Slightly observable observable observable observable observableobservable observable Evaluation A A A A A B B Example ComparativeExample 18 19 20 4 5 6 Colored photosensitive G108 G109 G110 G111 G112G113 resin composition Photosensitive resin layer 2.0 2.0 2.0 2.0 2.02.0 thickness (μm) Pigment coating amount 1.10 1.15 1.20 2.00 1.12 1.12(g/m²) C.I.P.G.36 0.77 0.81 0.84 1.40 0.78 0.78 Coating amount (g/m²)C.I.P.Y.150 0.33 0.35 0.36 0.60 0.34 0.34 Coating amount (g/m²) x 0.2930.297 0.301 0.280 0.303 0.303 y 0.634 0.626 0.618 0.656 0.614 0.614 Y52.1 54.4 56.6 45.7 57.8 57.8 ΔE 0 2.3 4.6 5.7 5.8 5.8 Coatingunevenness Not Not Not Not Not Observable observable observableobservable observable observable Display unevenness Slightly SlightlySlightly Slightly Not Observable observable observable observableobservable observable Evaluation B B B C C C(Unit: part)

TABLE 14 Example 11 12 13 14 15 16 17 Colored photosensitive B101 B102B103 B104 B105 B106 B107 resin composition Photosensitive resin layer2.0 2.0 2.0 2.0 2.0 2.0 2.0 thickness (μm) Pigment coating amount 0.750.74 0.70 0.67 0.65 0.75 0.74 (g/m²) C.I.P.B.15:6 0.67 0.66 0.63 0.600.59 0.67 0.66 Coating amount (g/m²) C.I.P.V.23 0.075 0.074 0.070 0.0670.065 0.075 0.074 Coating amount (g/m²) x 0.145 0.145 0.146 0.147 0.1470.145 0.145 y 0.082 0.084 0.088 0.092 0.094 0.082 0.084 Y 6.24 6.40 6.857.37 7.59 6.24 6.40 ΔE 4.0 2.9 0 3.2 4.6 4.0 2.9 Coating unevenness NotNot Not Not Not Not Not observable observable observable observableobservable observable observable Display unevenness Not Not Not Not NotSlightly Slightly observable observable observable observable observableobservable observable Evaluation A A A A A B B Example ComparativeExample 18 19 20 4 5 6 Colored photosensitive B108 B109 B110 B111 B112B113 resin composition Photosensitive resin layer 2.0 2.0 2.0 2.0 2.02.0 thickness (μm) Pigment coating amount 0.70 0.67 0.65 0.77 0.63 0.63(g/m²) C.I.P.B.15:6 0.63 0.60 0.59 0.69 0.57 0.57 Coating amount (g/m²)C.I.P.V.23 0.070 0.067 0.065 0.077 0.063 0.063 Coating amount (g/m²) x0.146 0.147 0.147 0.145 0.147 0.147 y 0.088 0.092 0.094 0.090 0.0970.097 Y 6.85 7.37 7.59 5.92 7.86 7.86 ΔE 0 3.2 4.6 6.3 6.3 6.3 Coatingunevenness Not Not Not Not Not Observable observable observableobservable observable observable Display unevenness Slightly SlightlySlightly Slightly Not Observable observable observable observableobservable observable Evaluation B B B C C C(Unit: part)[Production and Evaluation of Liquid Crystal Display Device]

Liquid crystal display devices were produced using the color filters ofExamples 11 to 20, and color filters of Comparative Examples 4 to 6. Itwas confirmed that the liquid crystal display devices using the colorfilters of Examples exhibit better display property than the liquidcrystal display devices using the color filters of Comparative Examples.

1. A colored photosensitive resin composition comprising analkali-soluble binder, a monomer or an oligomer, a photopolymerizationinitiator or a photopolymerization initiator system, and a coloringagent, wherein: the coloring agent comprises a pigment C.I.P.R.254 and apigment C.I.P.R.177; and when the colored photosensitive resincomposition is coated and dried to form a film with a thickness of 1 to3 μm, a quantity of the pigment C.I.P.R.254 in the film is 0.80 to 0.96g/m² and a quantity of the pigment C.I.P.R.177 in the film is 0.20 to0.24 g/m².
 2. A colored photosensitive resin composition comprising analkali-soluble binder, a monomer or an oligomer, a photopolymerizationinitiator or a photopolymerization initiator system, and a coloringagent, wherein: the coloring agent comprises a pigment C.I.P.G.36 and apigment C.I.P.Y150; and when the colored photosensitive resincomposition is coated and dried to form a film with a thickness of 1 to3 μm, a quantity of the pigment C.I.P.G.36 in the film is 0.90 to 1.34g/m² and a quantity of the pigment C.I.P.Y.150 in the film is 0.38 to0.58 g/m².
 3. A colored photosensitive resin composition comprising analkali-soluble binder, a monomer or an oligomer, a photopolymerizationinitiator or a photopolymerization initiator system, and a coloringagent, wherein: the coloring agent comprises a pigment C.I.P.B.15:6 anda pigment C.I.P.V.23; and when the colored photosensitive resincomposition is coated and dried to form a film with a thickness of 1 to3 μm, a quantity of the pigment C.I.P.B.15:6 in the film is 0.59 to 0.67g/m² and a quantity of the pigment C.I.P.V23 in the film is 0.065 to0.075 g/m².
 4. A photosensitive resin transfer material comprising atemporary support and a photosensitive resin layer provided on thetemporary support, wherein the photosensitive resin layer includes thecolored photosensitive resin composition of claim
 1. 5. A photosensitiveresin transfer material comprising a temporary support and aphotosensitive resin layer provided on the temporary support, whereinthe photosensitive resin layer includes the colored photosensitive resincomposition of claim
 2. 6. A photosensitive resin transfer materialcomprising a temporary support and a photosensitive resin layer providedon the temporary support, wherein the photosensitive resin layerincludes the colored photosensitive resin composition of claim
 3. 7. Acoating film of a colored photosensitive resin composition, wherein: thecolored photosensitive resin composition comprises an alkali-solublebinder, a monomer or an oligomer, a photopolymerization initiator or aphotopolymerization initiator system, and a coloring agent; the coloringagent comprises a pigment C.I.P.R.254 and a pigment C.I.P.R.177; acontent of the pigment C.I.P.R.254 in the coating film is 0.80 to 0.96g/m²; and a content of the pigment C.I.P.R.177 in the coating film is0.20 to 0.24 g/m².
 8. A coating film of a colored photosensitive resincomposition, wherein: the colored photosensitive resin compositioncomprises an alkali-soluble binder, a monomer or an oligomer, aphotopolymerization initiator or a photopolymerization initiator system,and a coloring agent; the coloring agent comprises a pigment C.I.P.G36and a pigment C.I.P.Y.150; a content of the pigment C.I.P.G36 in thecoating film is 0.90 to 1.34 g/m²; and a content of the pigmentC.I.P.Y.150 in the coating film is 0.38 to 0.58 g/m².
 9. A coating filmof a colored photosensitive resin composition, wherein: the coloredphotosensitive resin composition comprises an alkali-soluble binder, amonomer or an oligomer, a photopolymerization initiator or aphotopolymerization initiator system, and a coloring agent; the coloringagent comprises a pigment C.I.P.B.15:6 and a pigment C.I.P.V.23; acontent of the pigment C.I.P.B.15:6 in the coating film is 0.59 to 0.67g/m²; and a content of the pigment C.I.P.V.23 in the coating film is0.065 to 0.075 g/m².
 10. A color filter comprising a red (R)photosensitive resin layer, a green (G) photosensitive resin layer, anda blue (B) photosensitive resin layer, wherein the red (R)photosensitive resin layer comprises the colored photosensitive resincomposition of claim 1, the green (G) photosensitive resin layercomprises the colored photosensitive resin composition of claim 2, andthe blue (B) photosensitive resin layer comprises the coloredphotosensitive resin composition of claim
 3. 11. A color filtercomprising a red (R) photosensitive resin layer, a green (G)photosensitive resin layer, and a blue (B) photosensitive resin layer,wherein the red (R) photosensitive resin layer comprises the coatingfilm of claim 7, the green (G) photosensitive resin layer comprises thecoating film of claim 8, and the blue (B) photosensitive resin layercomprises the coating film of claim
 9. 12. A method of forming aphotosensitive resin layer, the method comprising adhering thephotosensitive resin transfer material of claim 4 to a substrate by alaminator.
 13. A method of forming a photosensitive resin layer, themethod comprising adhering the photosensitive resin transfer material ofclaim 5 to a substrate by a laminator.
 14. A method of forming aphotosensitive resin layer, the method comprising adhering thephotosensitive resin transfer material of claim 6 to a substrate by alaminator.
 15. A method for producing a color filter, the methodcomprising: forming a photosensitive resin layer; exposing thephotosensitive resin layer; developing the photosensitive resin layer;and baking the photosensitive resin layer, wherein the photosensitiveresin layer comprises the colored photosensitive resin composition ofclaim
 1. 16. A method for producing a color filter, the methodcomprising: forming a photosensitive resin layer; exposing thephotosensitive resin layer; developing the photosensitive resin layer;and baking the photosensitive resin layer, wherein the photosensitiveresin layer comprises the colored photosensitive resin composition ofclaim
 2. 17. A method for producing a color filter, the methodcomprising: forming a photosensitive resin layer; exposing thephotosensitive resin layer; developing the photosensitive resin layer;and baking the photosensitive resin layer, wherein the photosensitiveresin layer comprises the colored photosensitive resin composition ofclaim
 3. 18. A color filter produced by the method of claim
 15. 19. Acolor filter produced by the method of claim
 16. 20. A color filterproduced by the method of claim
 17. 21. A liquid crystal display deviceusing the color filter of claim
 18. 22. A liquid crystal display deviceusing the color filter of claim
 19. 23. A liquid crystal display deviceusing the color filter of claim 20.